CHINESE JOURNAL OF COMPUTATIONAL PHYSICS ›› 1999, Vol. 16 ›› Issue (4): 346-350.

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Calculations of overtones and com binations of ch 4 molecule using nonlinear quantum theory

Chen Xiangrong, Cheng Yan, Gou Qingquan, Pang Xiaofeng   

  1. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065
  • Received:1997-04-16 Revised:1999-01-04 Online:1999-07-25 Published:1999-07-25

Abstract: A simple three-parameter dynamical model in nonlinear quantum theory-the quant ized discrete self trapping equation is used to calculate the highly excited vi brational spectrum of CH stretches of CH4 molecule with up to total quantum number n=7. The results show the model calculations appear to describe the expe rimental data well.

Key words: CH4, vibrational energy spectrum, nonlinear quantum theory

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