CHINESE JOURNAL OF COMPUTATIONAL PHYSICS ›› 2013, Vol. 30 ›› Issue (2): 244-250.

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Monte Carlo Simulation of Nematic Droplets with Modified Gruhn-Hess Pair Potential

ZHANG Yanjun, WANG Chao, YE Wenjiang, ZHANG Zhidong   

  1. School of Sciences, Hebei University of Technology, Tianjin 300401, China
  • Received:2012-06-06 Revised:2012-10-12 Online:2013-03-25 Published:2013-03-25

Abstract: Nematic droplets are studied with Monte Carlo simulations with a modified Gruhn-Hess pair potential. The potential is spatially anisotropic and potential parameters are related to elastic constants K11 ,K22 ,K33 and surface-like elastic constant K13. It is assumed that nematic droplet surface is a free surface. Second order parameters and introrse intensity, which describes quantitatively intrinsic anchoring induced by surface at low temperatures, are calculated with a modified Gruhn-Hess pair potential and are compared with those in Gruhn-Hess model I. It is shown that the modified model with K13 induces intrinsic anchoring near droplet surface, orientation and intrinsic anchoring strength depend strongly on K13, and introrse intensity is related to K33/K11. Order degree of nematic droplet is lower from inner shell to outer shell due to incomplete anisotropic nematic-nematic interactions.

Key words: nematic droplets, Gruhn-Hess pair potential, Monte Carlo simulation, modified model, intrinsic anchoring

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