|
Study on ion dipole mixtures by use of cluster expansion method
Lu Guiwu, Zhou Kaixue, Chu Jun, Ren Lanting
CHINESE JOURNAL OF COMPUTATIONAL PHYSICS
1999, 16 (4):
351-357.
Based on the interaction of all particles in solution,a mixture of ions and point dipoles as an electrolyte solution is proposed.The partition functions,Virial coefficient and internal energy are calculated by using cluster expansion method. It is found that the partition function can be expanded in cluster integrals whi ch are easily calculated without three body interaction.Related numerical resul ts have been given and discussed.
Related Articles |
Metrics
|
|