Fully kinetic Particle-in-cell (PIC) simulations are performed to study the structure of collisional plasma shock waves with different Mach numbers. It is found that for low-Mach shocks, the spatial gradient of physical quantities near the shock front is gentle, corresponding to small Knudsen numbers, and the plasma transport properties (e. g. viscosity, heat flux) are well described by the classical transport theory. The simulated shock structure is consistent with that obtained from the numerical solution of the two-fluid equations. With increasing Mach numbers, the spatial gradient of physical quantities near the shock front becomes steep (i. e. the Knudsen number is increased), and the influence of kinetic effects on plasma transport properties become significant. For high-Mach shocks, kinetics effects come into play mainly in the following two aspects: (1) enhanced ion viscosity and heat flux due to the precursor ions and (2) nonlocal transport effects on the electron heat flux. Kinetic effects can significantly influence the shock wave structure by changing the plasma transport properties.